| 1. Identificação | ||||
| Tipo de Referência | Artigo em Revista Científica (Journal Article) | |||
| Site | mtc-m21c.sid.inpe.br | |||
| Código do Detentor | isadg {BR SPINPE} ibi 8JMKD3MGPCW/3DT298S | |||
| Identificador | 8JMKD3MGP3W34R/3RU9NSH | |||
| Repositório | sid.inpe.br/mtc-m21c/2018/10.04.11.04 | |||
| Última Atualização | 2018:10.04.11.04.54 (UTC) simone | |||
| Repositório de Metadados | sid.inpe.br/mtc-m21c/2018/10.04.11.04.54 | |||
| Última Atualização dos Metadados | 2021:03.06.19.29.57 (UTC) administrator | |||
| DOI | 10.5194/acp-18-12715-2018 | |||
| ISSN | 1680-7316 1680-7324 | |||
| Rótulo | self-archiving-INPE-MCTIC-GOV-BR | |||
| Chave de Citação | SantosLGKGOFLHBF:2018:BiBuEm | |||
| Título | Biomass burning emission disturbances of isoprene oxidation in a tropical forest  | |||
| Ano | 2018 | |||
| Mês | Sept. | |||
| Data de Acesso | 03 maio 2024 | |||
| Tipo de Trabalho | journal article | |||
| Tipo Secundário | PRE PI | |||
| Número de Arquivos | 1 | |||
| Tamanho | 3602 KiB | |||
| 2. Contextualização | ||||
| Autor | 1 Santos, Fernando 2 Longo, Karla Maria 3 Gunther, Alex 4 Kim, Saewung 5 Gu, Dasa 6 Oram, Dave 7 Forster, Grant 8 Lee, James 9 Hopkins, James 10 Brito, Joel 11 Freitas, Saulo | |||
| Identificador de Curriculo | 1 2 8JMKD3MGP5W/3C9JHKQ | |||
| Grupo | 1 CST-CST-SESPG-INPE-MCTIC-GOV-BR | |||
| Afiliação | 1 Instituto Nacional de Pesquisas Espaciais (INPE) 2 NASA Goddard Space Flight Center 3 University of California 4 University of East Anglia 5 University of East Anglia 6 University of York 7 University of York 8 Universidade de São Paulo (USP) 9 University of York 10 Universidade de São Paulo (USP) 11 NASA Goddard Space Flight Center | |||
| Endereço de e-Mail do Autor | 1 santos.f@mail.com | |||
| Revista | Atmospheric Chemistry and Physics | |||
| Volume | 18 | |||
| Número | 17 | |||
| Páginas | 12715-12734 | |||
| Nota Secundária | A1_MEDICINA_II A1_INTERDISCIPLINAR A1_GEOCIÊNCIAS A1_ENGENHARIAS_III A1_ENGENHARIAS_I A1_CIÊNCIAS_AMBIENTAIS A1_CIÊNCIAS_AGRÁRIAS_I A2_MATEMÁTICA_/_PROBABILIDADE_E_ESTATÍSTICA A2_ENGENHARIAS_II A2_ASTRONOMIA_/_FÍSICA | |||
| Histórico (UTC) | 2018-10-04 11:04:54 :: simone -> administrator :: 2018-10-04 11:09:50 :: administrator -> simone :: 2018 2018-10-04 11:11:49 :: simone -> administrator :: 2018 2019-01-04 16:57:12 :: administrator -> simone :: 2018 2019-01-07 14:25:38 :: simone -> administrator :: 2018 2021-03-06 19:29:57 :: administrator -> simone :: 2018 | |||
| 3. Conteúdo e estrutura | ||||
| É a matriz ou uma cópia? | é a matriz | |||
| Estágio do Conteúdo | concluido | |||
| Transferível | 1 | |||
| Tipo do Conteúdo | External Contribution | |||
| Tipo de Versão | publisher | |||
| Resumo | We present a characterization of the chemical composition of the atmosphere of the Brazilian Amazon rainforest based on trace gas measurements carried out during the South AMerican Biomass Burning Analysis (SAMBBA) airborne experiment in September 2012. We analyzed the observations of primary biomass burning emission tracers, i.e., carbon monoxide (CO), nitrogen oxides (NOx), ozone (O-3), isoprene, and its main oxidation products, methyl vinyl ketone (MVK), methacrolein (MACR), and isoprene hydroxy hydroperoxide (ISOPOOH). The focus of SAMBBA was primarily on biomass burning emissions, but there were also several flights in areas of the Amazon forest not directly affected by biomass burning, revealing a background with a signature of biomass burning in the chemical composition due to long-range transport of biomass burning tracers from both Africa and the eastern part of Amazonia. We used the [MVK + MACR + ISOPOOH] / [isoprene] ratio and the hydroxyl radical (OH) indirect calculation to assess the oxidative capacity of the Amazon forest atmosphere. We compared the background regions (CO < 150 ppbv), fresh and aged smoke plumes classified according to their photochemical age ([O-3] / [CO]), to evaluate the impact of biomass burning emissions on the oxidative capacity of the Amazon forest atmosphere. We observed that biomass burning emissions disturb the isoprene oxidation reactions, especially for fresh plumes ([MVK + MACR + ISOPOOH] / [isoprene] = 7) downwind. The oxidation of isoprene is higher in fresh smoke plumes at lower altitudes (similar to 500 m) than in aged smoke plumes, anticipating near the surface a complex chain of oxidation reactions which may be related to secondary organic aerosol (SOA) formation. We proposed a refinement of the OH calculation based on the sequential reaction model, which considers vertical and horizontal transport for both biomass burning regimes and background environment. Our approach for the [OH] estimation resulted in values on the same order of magnitude of a recent observation in the Amazon rainforest [OH] congruent to 10(6) (molecules cm(-3)). During the fresh plume regime, the vertical profile of [OH] and the [MVK + MACR + ISOPOOH] / [isoprene] ratio showed evidence of an increase in the oxidizing power in the transition from planetary boundary layer to cloud layer (1000-1500 m). These high values of [OH] (1.5 x 10(6) molecules cm(-3)) and [MVK + MACR + ISOPOOH] / [isoprene] (7.5) indicate a significant change above and inside the cloud decks due to cloud edge effects on photolysis rates, which have a major impact on OH production rates. | |||
| Área | CST | |||
| Arranjo | urlib.net > BDMCI > Fonds > Produção pgr ATUAIS > CST > Biomass burning emission... | |||
| Conteúdo da Pasta doc | acessar | |||
| Conteúdo da Pasta source | não têm arquivos | |||
| Conteúdo da Pasta agreement |
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| 4. Condições de acesso e uso | ||||
| URL dos dados | http://urlib.net/ibi/8JMKD3MGP3W34R/3RU9NSH | |||
| URL dos dados zipados | http://urlib.net/zip/8JMKD3MGP3W34R/3RU9NSH | |||
| Idioma | en | |||
| Arquivo Alvo | santos_biomass.pdf | |||
| Grupo de Usuários | simone | |||
| Grupo de Leitores | administrator simone | |||
| Visibilidade | shown | |||
| Política de Arquivamento | allowpublisher allowfinaldraft | |||
| Permissão de Atualização | não transferida | |||
| 5. Fontes relacionadas | ||||
| Unidades Imediatamente Superiores | 8JMKD3MGPCW/449U4PL | |||
| Lista de Itens Citando | sid.inpe.br/mtc-m21/2012/07.13.14.53.10 3 sid.inpe.br/bibdigital/2021/03.06.05.18 1 | |||
| Divulgação | WEBSCI; PORTALCAPES; AGU; SCOPUS. | |||
| Acervo Hospedeiro | urlib.net/www/2017/11.22.19.04 | |||
| 6. Notas | ||||
| Campos Vazios | alternatejournal archivist callnumber copyholder copyright creatorhistory descriptionlevel e-mailaddress format isbn keywords lineage mark mirrorrepository nextedition notes orcid parameterlist parentrepositories previousedition previouslowerunit progress project readpermission rightsholder schedulinginformation secondarydate secondarykey session shorttitle sponsor subject tertiarymark tertiarytype url | |||
| 7. Controle da descrição | ||||
| e-Mail (login) | simone | |||
| atualizar | ||||